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[personal profile] yubsie
I must say "too much junk in the trunk" is not a rationale I've seen before for why SN2 reactions don't go at tertiary carbons. My usual way of explaining it is "it's too squishy".

The word squishy gets used a lot in mechanism discussions. Certainly more often than the word bendy, which also comes up from time to time. And good old "hates its life".

Also...




It's such a shame John Barrowman is so shy, eh?

(The boxers are currently at 2050 pounds. :p)

(no subject)

Date: 2009-11-23 01:24 am (UTC)
From: [identity profile] helplessdancer.livejournal.com
I've decided to just stop being surprised at what John Barrowman does anymore. It's easier this way. :P

(no subject)

Date: 2009-11-23 09:28 pm (UTC)
From: [identity profile] roysbrat.livejournal.com
OMG he's so adorable. I just finished watching the end of DW S3, and I really fell in love with him :)

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